Sahih Bukhari | Volume 8 | Hadith Number 411

Narrated by Abu Huraira
The Prophet said, "When the Imam says 'Amin', then you should all say 'Amin', for the angels say 'Amin' at that time, and he whose 'Amin' coincides with the 'Amin' of the angels, all his past sins will be forgiven."